phen相关论文
随着分子生物学的发展,许多生物无机化学家基于多元混配化合物在生命活动中扮演的重要角色,开始着手于多元配合物从合成到结构......
Charcot-Marie-Tooth(CMT) disease is a common neurogenetic disorder and its heterogeneity is a challenge for genetic diag......
三新 mixed-ligand Fe ( II/III )建筑群[ Fe2 ( 2-btec )( 2-H2btec )( phen ) 2 ( H2O ) 2 ] n ( 1 ),[ Fe2 ( btec )( phen ) 2......
Coordination compounds of lanthanide trichloroacetates with 1,10-phenanthroline weresynthesized and characterized as Ln......
反应唯一[W (CN )(phen ) 6 与一个有磁力地各向异性的 Mn Schiff 底产出 WV (5d )-MnIII(3d) 有线性链结构的二金属的化合物。链......
Static field induced magnetic relaxations in dinuclear lanthanide compounds of [phen2Ln2(HCOO)4(HCOO
二 dinuclear lanthanide (行) 建筑群,是提出了[phen2Ln2 (HCOO ) 4 (HCOO ) 22x (NO3 ) 2x ](1,行 = Gd 和 x = 0.52;2,行 = 嗯并且 ......
合成了一个单核铜-邻菲啰啉配合物[Cu(phen)(C2O4)H2O].H2O,培养了配合物的单晶并通过X-射线衍射解析了其晶体结构.晶体结构研究表......
由二苯甲酮-4,4′-二甲酸和邻菲咯啉为配体合成了1个新的镉化合物[Cd(bpndc)(phen)2(H2O)].2H2O(1)(H2bpndc=二苯甲酮-4,4′-二甲......
利用混合配体(H2tda=亚硫基二乙酸,H2ox=乙二酸,phen=1,10-菲咯啉)与CeCl3.5H2O反应,合成了新型稀土配合物[Ce(tda)(ox)0.5(phen)]......
采用溶液法合成了分子式为[Cu2(phen)2(OH)2(H2O)2][Cu2(phen)2(OH)2Cl2]Cl2.6H2O的配合物。通过元素分析、红外光谱、紫外光谱和X......
3,5-二氨基苯甲酸(diaba),1,10-邻菲啰啉(phen)与过渡金属镉经水热反应合成了一个新型的镉配合物[Cd(diaba)(phen)2]NO3·H2O(1),......
以2-(对甲基苯甲酰基)苯甲酸(2-PMBBA)和1,10-邻菲啰啉(Phen)为配体合成了一个新的锌(Ⅱ)配合物Zn(2-PMBBA)2(Phen)。该配合物晶体......
Graphene has the advantages of high electrical conductivity,high heat conductivity,and low noise,which makes it a potent......
以3,3’,4,4’-偶氮苯四羧酸(ABTC)和1,10-菲罗啉(Phen)为配体,采用常规溶剂挥发法合成了新颖单桥配合物[Co2(ABTC)(Phen)2(H2O)6]......
牛磺酸和邻香草醛在甲醇中于0℃反应4 h制得牛磺酸缩邻香草醛席夫碱(TMSSB);以TMSSB和邻啡罗啉(phen)为混合配体经水溶液法合成了......
以2,2′-联吡啶-3,3′-二羧酸为配体合成了一个稀土-有机功能配合物[Tb2(C12H6O4N2)3(Phen)2(H2O)2.6H2O]n,并用X射线单晶衍射仪测......
Hydrothermal Synthesis, Crystal Structure and Fluorescence Properties of a Three-dimensional Triply-
The novel complex [Zn2(Mba)3(Phen)2EtOH)]·ClO4 (Hmba=methoxybenzoic acid, Phen=1,10-phenanthroline, EtOH=ethanol) was s......
Design,synthesis characterization and in vitro biological activity of a series of 3-aryl-6-(bromoary
Bromination is used as a strategy to improve biological activity in medicinal chemistry.In order to study on the structu......
以5-羟基间苯二甲酸(HO-H2bdc)、5-甲基间苯二甲酸(m-H2bdc)和1,10-菲啰啉(phen)为配体,在水热条件下合成了饵金属-有机骨架[Er2(H......
新制备的Cu(OH)2·yH2O加入到溶有2-甲基苯甲酸、邻菲咯啉的C2H5OH/H2O(1∶1,V/V)混合溶剂中反应,得到一新的铜配合物[Cu(phen)2(C......
在水热条件下,用Na10[α-SiW9O34]·18H2O,Fe2(SO4)3与phen反应合成了一种有机-无机杂化Keggin型硅钨酸盐[FeII(phen)3]2[α-SiW12......
以3,3’,4,4’-偶氮苯四羧酸(ABTC)和1,10-菲罗啉(phen)为配体,金属Zn(Ⅱ)为配位中心,采用溶剂挥发法在乙醇水中合成了新型夹心双......
Synthesis, Crystal Structure and Fluorescent Property of One New Complex [Na_2(2-benzoylbenzoato)_4(
One binuclear sodium(Ⅰ) complex [Na2(2-benzoylbenzoato)4(Phen)2(H2O)2]·H2O has been synthesized with 2-benzoylbenzoic ......
Crystal Structure,Fluorescence and Thermal Stability Properties of a Dinuclear Copper(Ⅱ) Complex[Cu_
A new dinuclear copper(Ⅱ) complex[Cu2(L)2(phen)2]·5H2O(1) with bicycle[2.2.1]hept-2-en-5,6-dicarboxylic acid(H2L) and ......
合成了一种锌配位聚合物{[Zn(H2O)2(L)(phen)].3H2O}n(1),其中,H2L=1-氨基-8-萘酚-3,6-二磺酸并利用元素分析、红外、紫外、荧光、......
合成了一种新型的配合物{[Cu(Phen)(Nap)_2]_2·(EtOH)_2·(H_2O)_2}(Phen=1,10-菲咯啉,Nap=1-萘甲酸,EtOH=乙醇)。通过元素分析、......
A new europium(III) complex Eu(L)3(Phen)2(1) with 2-benzoylbenzoic acid(HL) and 1,10-phenanthroline(Phen) as ligands has......
Dicyanide building block cis-Fe(phen)_2(CN)_2 and [Mn~Ⅲ(salen)](ClO_4) have been used to design and synthesize a cyanid......
测定痕量汞的分析方法很多,其中以冷原子荧光法的灵敏度为最高,使用不同挡次的仪器,检测限约在10~(-10)~5×10~(-11)g/ml范围,是一......
本文在乙醇-水溶液中合成了H_2DBA及phen、[OH]~-与希土离子的混配配合物Ln(HDBA)_2(OH)(phen)·H_2O(Ln=La、Pr、Nd、Sm、Eu、Gd......
Investigations on Preparation,Crystal Structure and Thermal Stability of Bis(O-ethylcarbonodithiolat
[Co(Et XA) 2·phen]·H 2O was prepared by adding 1,10 phen~anthroline to the EtOH solution of bis( O ethylcarbo~......
A novel compound Ni(phen)(H2O)(V2O6) has been hydrothermally synthesized and structurally determined to be a two-dimensi......
A cadmium complex [Cd(cinnamato)2(Phen)]2 was synthesized by the reaction of cinnamic acid, phenanth-roline (phen), and ......
·AIM: To identify the pathogenic mutations in a Chinese pedigree affected with Usher syndrome type II(USH2).· METHODS:......
Crystals of the title compound were prepared, whose structure has been determined by X-ray diffraction as a biscrown co......
本文研究了用Ag(Ⅰ)——phen——TBF——CTMAB多元络合物测定微量银的新方法、该络合物在PH2.52—5.31范围的最大吸收波长为545nm......
使用较高浓度的邻菲咯啉和抗坏血酸掩蔽mg量的镓,提高了胶束增溶光度测定镓中铝的选择性,从而简化了分离手续,改善了精密度。
The......
铬天清S是一种比较优良的显色剂,能与多种金属离子发生显色反应,在胶束增溶光度法中得到了极为广泛的应用,在多元络合物显色反应的......
2—噻吩甲酰三氟丙酮(TTA)和诸如三正辛基氧化膦(TOPO)、邻菲罗啉(phen)等中性附加配位体所组成的协同萃取体系已应用于荧光分析......
本文提出了在碱性介质中,基于Ag(I)-phen-TPPS_4配合物的生成而建立高灵敏度测定Ag(I)的分光光度法。配合物的最大吸收波长为438nm......
本文利用“补偿法”测定了电对 Fe(phen)3_-~(3+)/Fe(phen)3_-~(2+)和 Cu(phen)3_-~(2+)/Cu(phen)_-2~+(phen 为邻菲绕啉)的标准电......
本文对Gd和Sm—TTA—Phen—TritonX—100体系的共发光现象进行了较详细的研究,试验了实验条件的影响(pH、TTA、Phen、Gd、表面活性......
本文研究了天冬氨酸(以AA表示)-KBrO_3-Mn~(2+)-Fe(Phen)_3~(2+)(Phen表示邻菲罗啉)-H_2SO_4为体系的化学振荡反应,达种以氨基酸......